Corrosion Chemistry by George R. Brubaker and P. Beverley P. Phipps (Eds.)

By George R. Brubaker and P. Beverley P. Phipps (Eds.)

Content material: Corrosion : the main normal challenge of fabrics technological know-how / Donald Tuomi -- Electrochemical innovations in corrosion stories / Francis M. Donahue -- High-temperature corrosion / J. Bruce Wagner, Jr. -- Ionic and digital conduction in nonmetallic levels / John W. Patterson -- Dissolution of iron / Morris Cohen -- Ferrous passivation / V. Brusic -- Corrosion of valve metals -- J.E. Draley -- The position of water in atmospheric corrosion / P.B.P. Phipps and D.W. Rice -- Corrosion inhibition and inhibitors / Rudolf H. Hausler -- Stress-corrosion cracking / J.C. Scully -- commercial difficulties : cooling water and cooling-water remedy / J. Fred Wilkes -- High-temperature corrosion in coal gasification vegetation / V.L. Hill, D. Yates, and B.A. Humphreys

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Example text

The s i g n s o f t h e r a t e and f l u x terms in E q u a t i o n 29 s h o u l d be a d j u s t e d t o accomodate t h i s s i g n convention. The r a t e ( c u r r e n t ) o f an e l e c t r o c h e m i c a l r e a c t i o n is d e s c r i b e d by t h e sum o f t h e r a t e s ( c u r r e n t s ) o f t h e a n o d i c and c a t h o d i c r e a c t i o n s w h i c h c o n s t i t u t e t h e e l e c t r o d e r e a c t i o n . The a n o d i c and c a t h o d i c c u r r e n t s , representing "parts" of the o v e r a l l current (rate), are called p a r t i a l currents.

Transport Controlled Electrode and t h e Reactions. As n o t e d above from t h e s u r f a c e is r e a c t i o n . The c o n v e c t i v e mass t r a n s p o r t e q u a t i o n s w h i c h d e s c r i b e t h i s m a t e r i a l f l u x ( i n terms o f c u r r e n t d e n s i t y and c o n s i s t e n t w i t h t h e s i g n c o n v e n t i o n p r o posed in t h i s c h a p t e r ) a r e i = (n/|v R e d |)Fk ([Red] -[Red] ) c b s (38) and i = -(n/|v |)Fk ([0x] -[0x] ) 0 x c b s (39) where k is the mass t r a n s f e r c o e f f i c i e n t and t h e subs c r i p t s b and s r e p r e s e n t t h e b u l k and i n t e r f a c i a l c o n c e n t r a t i o n s , r e s p e c t i v e l y .

The c a r e f u l c o n t r o l o f c o n d i t i o n s r e s u l t s i n an amaz­ i n g l y homogeneous f i l m growth o f h i g h s e m i c o n d u c t o r q u a l i t y . The i m p e r f e c t i o n s t r u c t u r e i n a c o m p o s i t i o n and s t r u c t u r a l sense depends on t e c h n i q u e d e t a i l s . The second example i s e l e c t r o l y t i c p l a t i n g o f copper f i l m s . C o n t r a r y t o some e x p e c t a t i o n s growth c l o s e t o e q u i l i b r i u m p o t e n t i a l c o n d i t i o n s does n o t r e s u l t i n the h i g h e s t q u a l i t y d e p o s i t .

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