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1977, 3187. Corey, E . J . ; Ulrich, P. Tetrahedron Lett. 1975, 3685. Leroux, Y. ; Mantione, R. Tetrahedron Lett. 1973, 2586. C. ; Linstrumelle, G. Tetrahedron Lett. 1978, 1137. C. R. Synthesis. 1979, 132. Bell, A. ; Davidson, A H. ; Earnshaw, C. K. S. ; Warren, S. J . Chem. Soc. Comm. 1978, 988. Blatcher, P. I. ; Warren, S. J. Chem. Soc. Comm. 1978, 657. Corbel, B. P. ; Dreux, M. ; Savignac, P. Tetrahedron Lett. 1976, 835. F. J. Tetrahedron Lett. 1977, 3875. I. V. A. V. Zhur. Org. Khim. 1974, 10.
M I D U R A , M . P O P I E L A R C Z Y K , and J. OMELAŃCZUK Center of Molecular and Macromolecular Studies, Polish Academy of Sciences, Depart ment of Organic Sulfur Compounds, 90-362 Łódź, Boczna 5, Poland The ambident behaviour of sulfur in terms of its ability to stabi1ize adjacent negativ de this element a focal point for new reagents and reactions (1). For this reason our concern has focused on the synthesis of new phosphonates containing sulfur and selenium and the exploration of their application in synthetic and stereochemical studies.
I. V. A. V. Zhur. Org. Khim. 1974, 10. 167. J. P. ; Christol, H. Synthesis, 1979, 538. J. P. ; Christol, H. Tetrahedron Lett. 1979, 2377. RECEIVED June 30, 1981. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1981. 13 Monomeric Metaphosphates in Enzymic and in Enzyme-Model Systems F. H. : In the presence of water or other nucleophiles, monomeric meta phosphates y i e l d orthophosphates CH OPO + H O —> 3 2 CH OPO H 2 3 PO + H O —> H PO3 2 2 4 3 + - H (3) + +Η (4) + The evidence for the mechanism shown above derives from rate data.