Advances in Catalysis and Related Subjects, Volume 4 by W G Frankenberg

By W G Frankenberg

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Thus the chromate catalysis, which on the face of it is an example of the intermediate product mechanism, is more complex than the simple theory implies, and it is probable that in certain circumstances the reduction CrV1+ CrIT*and the reverse oxidation also occur, suggesting that compensating reactions are also important. On the other hand, the kinetics of the halide catalyses, which have been the main basis for the theory of compensating reactions, appear from more recent work to indicate the participation of intermediates probably of a peroxidic nature.

Pew, A. , and Peters, W. , Petroleum Refiner 17, No. 11, 574 (1938). 3. Simpson, T. , Evans, L. , Hornberg, C. , and Payne, J. , Proc. Am. Petroleum Znst. 24 [111],83 (1943). 4. Murphree, E. , Brown, C. , Fischer, H. G. , Gohr, E. , and Sweeney, W. , Znd. Eng. Chem. 36, 768 (1943). 5. , Kolloid-2. 11, 17 (1912). 6. , Erdol u. Teer 2, 265, 411 (1926). 7. , J . Sac. Chem. Znd. (Japan) 40, 54 (1927). 8. Thiele, F. , German Patent 373,060 (1923); Erdoel u. S. Patent 1,671,573 (1928); Leamon, W. S.

Plank, C. , J . Colloid Sci. 2, 413 (1947). 47. Hansford, R. , Gordon Research Conference on Catalysis, New London, N. , June 24, 1948. 48. Greensfelder, B. , Voge, H. , and Good, G. , Znd. Eng. Chem. 41, 2573 (1949). 49. Evans, A. , J . Chem. Soe. 252, 1947. 50. Voge, H. , Good, G. , and Greensfelder, B. , Znd. 1Sng. Chem. 38, 1033 (1946). 51. , and Wackher, R. , J . Am. Chem. Soc. 68, 595 (1946). 52. , Hammel, E. , and Taylor, H. , J . Am. Chem. 70, 2269 (1948). 53. , and Smith, R. , Nature 167, 874 (1947); J.

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