By CFA Institute
The CFA software point II Curriculum is geared up into numerous examine classes to aid applicants navigate the cloth. each one research consultation contains assigned readings (drawn from textbook chapters, specialist magazine articles, CFA Program-commissioned content material, instances, and learn analyst reports); studying end result statements; and challenge units that exhibit useful program and make stronger figuring out of the thoughts provided within the readings. For comfort, the assigned readings are assembled into a number of self-contained volumes. CFA has: * Sequenced the readings in conformity with the research periods * Reprinted the pertinent studying end result statements sooner than every one examining * further learn assets, equivalent to a far better define, a finished index, and a unified word list * published the curriculum in two-color structure to complement the appearance and readability of the indicates, tables, and required as opposed to non-compulsory remedies
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Additional info for 2011 CFA Program Curriculum: Level 2, Volume 4
Similar observations had already been made with iV-allylnormorphine (159,160) # As attempts to resolve racemic 3-hydroxy-iV-allyl-morphinan into its optical antipodes were unsuccessful, the (—)-enantiomer was obtained from (—)-3-hydroxy-7V-methyl-morphinan by means of cyanogen bromide decomposition (153) according to VON BRAUN. (135) (136) N-CN (137) (138) (139) T h e 3 - h y d r o x y g r o u p o f (—)~3-hydroxy-iVHm£thyl~morphinan is a c e t y l a t e d a n d t h e p r o d u c t (135) t h e n t r a n s f o r m e d w i t h c y a n o g e n b r o m i d e i n t o t h e c y a n i d e (136).
P. ,P* dl9 a dl, a — 69, af + 71, a -62-2, af + 60-8, a dl* -142* 2 (-) + 140 -18 + 18 + 14 -14 Ref. 133 133 133 133 133 133 133 133 133 133 133 133 133 133 180 295 295 295 295 295 295 295 295 o w C/2 TABLE IV. p. Ref. 6-dehydro CH3O 6 z! 6-dehydro-10,l 6-dioxo 167-170° C 1 8 H 1 9 O3N dl 173 CH3O 6,7-dimethyl-zl 6 - d e h y d r o - l 0,16- 179-181° C 2 0 H 2 3 O3N dl 173 base 184-186° C 1 9 H 2 5 ON m 173 iodo- 217-219° C 2 0 H 2 8 ONI dl 173 dl dioxo CO HO 6,7-dimethyl-zl6-dehydro HO 6,7-dimethyl-zJ 164-166° 6 -dehydro methylate HO base 217-218° C 1 7 H 2 3 ON HO iodo- 224-225° C 1 8 H 2 6 ONI methylate t Stiong analgesic activity * W e a k or n o analgesic activity > \ ) s s e .
S T R U C T U R E OF THE BY-PRODUCTS OF THE M O R P H I N A N SYNTHESIS O n c y c l i z a t i o n o f 1 - b e n z y l o c t a h y d r o i s o q u i n o l i n e s t h e d e s i r e d JV-subs t i t u t e d 3 - h y d r o x y m o r p h i n a n s a r e o b t a i n e d in a b o u t 6 0 p e r c e n t yield. T h e m o t h e r l i q u o r s yield b y - p r o d u c t s p o s s e s s i n g t h e s a m e e m p i r i c a l f o r m u l a a s the corresponding morphinans. p. 209-210 °C) obtained consistently in a yield of 10 to 15 per cent during the preparation of (+)-3-hydroxy-iV~methylmorphinan is ( + )-6-methyl-10-hydroxy-l,2,3,3a,5,6,6a,7,l lb,l lc-decahydro-4#-dibenzo [d, g] quinoline (175).